HomeMy WebLinkAbout14 Goose Lane - 6/9/1992R z -9eAa� a JWo aw xGGU/L&xe
yew �./r�na ll/ �, � 06uP//mmtPgLC vP/YG"
700 Vag Y4.P.l, loe0,00z 02202
Mr. Scott Leite, Health Agent V�'June 9, 1992
Mansfield Board of Health y%
>C)U
50 West Street Mansfield, MA 02048
Dear Mr. Leite,
On May 22, 1992„ Ron Wancour, Chemlawn, called regarding the
incident in Mansfield which occurred that morning, to which you
refer in your May 28, 1992 letter. Although Mr. Wancour was the
only manager on duty at the Easton branch at the time of the
incident, the Branch Manager is Robert Jones. The applicator was
John Delgado, license # 17722.
It is our understanding that the "spill" leading to the drain
was a result of Mr. Delgado cleaning his hands with fresh water
after dealing with a small leak in his hose. We were told that the
liquid fertilizer and Dursban mix which was involved, Lesco Pre-M
60 DG Herbicide, EPA REG NO: 10404-52, with a small amount of
Dursban Turf Insecticide, EPA REG NO: 464-524, had evaporated,
negating any cleanup procedure.
Again, according to the account received on May 22, Mr. Delgado
was not aware of the granular material falling from his vehicle.
After you notified Chemlawn, Mr. Wancour went to the site and
cleaned up any remaining material.
The dry material that fell from the cargo box as Mr. Delgado
drove away was; Lesco 32-5-7 Fertilizer with Dursban, EPA REG NO:
10404-29. The material is essentially a fertilizer with 0.74%
chlorpyrifos, which does make it a pesticide.
Chemlawn has inspected the vehicle and is of the opinion that
the fertilizer fell from the cargo box, possibly as a result of the
latch not being completely engaged. Chemlawn now has added an
elastic cord to further secure these latches.
Chemlawn reported the incident to the Pesticide Bureau as
required by 333 CMR 10.15(1)(i). The Bureau has addressed the
incident with Mr. David Gibson, Chemlawn's Area Technical Manager.
Based on the information available at this time, no further action
in this matter is being considered. If you have any further
questions, or if we can be of help, please do not hesitate to
contact the Bureau at 617-727-3020.
Your ruly,
/'
¢�o n Kenney
/ Chief Inspector
Pesticide Bureau
t Er
rAll
t�" - I 4/ f
May 29, 7992
John Keeney
Commonwealth of Massachusetts
Pesticide Bureau
100 Cambridge St..
Boston, Ma, 02202
Dear Mr. Keeney,
On May 22, 1992, at 9:30 AM, John Delgado (ChemLawn
Specialist, Pesticide License #17722) had a 1 - 2 gallon
spill of nitrogen, phosphates, potassium, dilute
pendimethalin 60 DG (10404-52) and dilute dursban (508-261-
7366) at 14 Goose Lane, Mansfield, Ma.
The cause of release was a small pinhole in the delivery
hose to the second reel. With the spray system under
pressure at the time of the spill, a stream of spray stained
the sidewalk and the rest was spilled in the street. With
the temperature in the low 80's at the time, the spill
basically spread and evaporated. John then closed off the
delivery to this reel and proceeded to spray the lawn with
the front reel.
Prior to leaving, John used approximately 2 gallons of water
out of a water jug on the tanker bed to wash his hands.
This "stream" of water ran 25 feet to a stormdrain. As John
left the property, a small quantity of dry, Lesco 32-5-7
dursban pellets fell onto the street. This "spill" was
reported to me by Scott Lee (Mansfield Board of Health). I
went to the site, finished cleaning up all the dry pellets
and washed the "stream" with soap and water, blocking the
storm drain with a Hazorb pillow to prevent any water from
going into the drain. I stayed at the site until the water
had completely dried.
Yours truly,
lor,
Ron Wancour Delgga
Field Service Manager - Lawn.-S,p st
Post-Ir" brand fax transmittal memo 7WI 1#0rPages r.
ToIt i 1
Y
iwm '" i�^
Co.
Co.
Dept.
Phone #
Fex #
Fax #
June 4, 1992
John Kenney
Commonwealth of Mass
Pesticide Bureau
100 Cambridge Street
Boston, Ma. 02202
Dear Mr. Kenney,
Faxed to you today is more information regarding the May 22,
1992, spill at 14 Goose Lane, Mansfield, Ma:
1) "Route Card": Copy of permanent customer record. used
for documentation of each visit by specialist.
2) Invoice copy
3) Fill chart copy
4) Lesco 32-5-7 fertilizer with dursban label copy
5) ChemLawn's spill report copy
Specialist John Delgado remained at the site until the spill
had dried (sidewalk area and street). He was unaware of the
dry material spill.
We believe the dry material (32-5-7 fertilizer with dursban)
fell out of the cargo box as the truck pulled away ptfter he
serviced the customer's property. Cargo boxes now nave a
bungy cord holding latches down and secure.
Please contact me if there is anything else you need from
ChemLawn.
Yours truly,
&
Ron Wancour
Field Service Manager
ChemLawn Services Corporation • 15 Plymouth Drive - P.O. Box 186
South Easton, Massachusetts 02375 • (508) 238-6931 South Easton • 1�800-888-0639
Ala L- D- 1- 11
mpleb ChamLawn Spgl Repom ' �
realer loan Sgallons.Nrmed
vrr R1c uJC VIVLY
REPORT REVIEWED 6Y:
pesucide or fenilrzer Spills.
tfills edng a9mrmS nysitOOtly0lieLSPILL REPORT
N r"I"' =„91nq any spill.udem
LA
Regional Technical Manage!Ail
Corporal° Ta.hmcat Director
cdeYng any spill.
COlpefate Safety Manager _w
REPORT PREPARED BY: If%1
Imanlenance aNerycomyiaree nawgerf
DATE: -.
BRANCH: _SQjb 139
e nemmr A wine
TRUCK NUMBER; S IFf I
EMPLOYEES) INVOLVED: 1040 VEi (AQp LA_Wv�l
ame file
DATE OF SPILL:
TIME OF SPILL::
ADDRESS OF SPILL: —lif GO&SEeBL ill PYr/tl7r/F soleAIA till.
�a��a��
TOTAL A or LES. SPILLED:
Q EXACT QUANTITIES F EACH COMPONENT SPILLED: (from worksheet) FILL CHART CODE:
i Nitrogen Phosphate lb. PIb.N MCPA lb.a.i,
205 MCPP Ib.a.i.
Potassium Ib.K.O Dicamba Ib.a.i.
Iron,� Ib.Fe Dursbane Ib.a.i.
PreZv---LJ. �lJ l / Ib,a.i. Diazinon Ib.ai.
. Atrazine Ib,a.i. Sevin*lb.a.i.
Morestano Ib.a.i,
Orthenelb
_ Ib.a.i.
Benomyl Ib.a.i.
Mancozeb _lb.a.i.
Other
Other
3 SPECIFIC CAUSE OF SPILL (check as many as appropriate)
EQUIPMENT: HUMAN FACTOR:
CDHose Break ElVandalism
._../ where ❑ Inattention
I� Fitting Break O Improper Maintenance
where �LId1QEId/iQE�- explain
._ Gun U Improper Operation
O Hose Clamp Failure explain
❑ band clamp. [ screw clamp CJ Insufficient Training
u Agitator Seal 0 Vehicle Accident
4 Was Spill Contained? yes%rnoC --'
PATH OF SPILL
O entered Storm Drain
❑ Entered Body of Water
❑ Entered Swimming Pool
O Entered Roadside Ditch
❑ Absorbed Into Soil
C Other
ApDDITIONAL COMMENTS:
ieE1:11MAT uu:Wfi p�etnt AQm
G Valve C Other
011
wher
� other IFS5-
4
s01'9aee tlMrtllh7lAt A SratD. ORAIA!
5 TIME OF ARRIVAL OF SPILL TEAM; TOTAL tbpL!or LBS. RECOVERED:
DESCRIBE METHODS AND PROCEDURES USED TO CLEAN SPILL:Q[_HAZORB
VY LaW BQ�Mi
DOES YOUR BRANCH HAVE A TRAINED SPILL RESPONSE TEAM? X yes
❑ no
DOES YOUR BRANCH USE ABSORBANT PILLOWS? 91 yes ❑ no
DOES YOUR BRANCH HAVE A SPILL CLEAN UP KIT? (for emergency use only)
CKyes C no i
,DESCRIBE ANY OTHER CIRCUMSTANCES OR PROBLEMS:
I
i
61 CONTACT LOCAL AND FEDERAL AGENCIES AS PER REGIONAL TECHNICAL MANAGER'S INSTRUCTIONS. ------—,
Agencies Notified ate 8 Time Contact Person Action Taken by Each Agency
t.�If�BalpO — ,�i(-(ELV�( IIJf4F4trLe�!
I
PAPER FLOW: xePp Acopy W me Brehm. $ena the SPILL REPORT To THE W1�11CT MUST BE REeIBWED BY TIIE IiRANCM MW:AGER
11l REGIONAL TECHNICAL MANAGER
121 CORPORATE SAFETY MANAGER
8•S 1 ngnalura
1`41,n Rn J e9
Fp(m ,J;p
�11
11140
CMALANN
Time
1i Am
ruovT(-AT, cnTT.T.
Location
�Wz��.. u;... a.i
Incident description:
04WITY F
34-5-7 3 ((/ &AF&J-6p
riaLerial released, type--
—lL°Yi1�LCN
-5.1 *0 -Vt
Fill code:
Duration of Spill:.
ID SE[.idQSy
Weather conditions:
-ay
IIrlur�S�S°
DATA WOJJKSHh.Wj
Persons Injured
by"4-hMA 506-,U1-7366
OWip ODA we/ 5wcau5t OJdEAwAY.-- --
Material released, quantity:
CiAj , nnlS /EDRY__ _
Cause of release:
Present and anticipated movement:
Personnel on the scene
JWA) 00- 400 ' 0 777- a -
Action Initiated: r to contact on scene and phone #
�AU55T Omit- Th ��ia i&L. AbED. WA
Decide if additional assistance is needed:
If more gallons spilled than specialist can clean up alone
Send pickup with spill pallet
If more than 30 gallons spilled send spill response tanker
COMMUNICATE INFORMATION
Dave Gibson - Beeper# 1 (800) 512 2608
Notify Branch Manager
Notify ATM, ASFM, or another ATM
Notify Ben Cheverko at Corp..extention 1 (800) 888 3572 ext. 4603 if:
1
• over 300 gallon tank loss 50 gal concentrated pesticide loss
50 lbs dry pesticide(15% active ingredient) 1.000 gal base mix
• is an area of high environmental impact enters sewer or waste water
ChemLswn Services Cotpantlon • 4 Kunihe(m Ddv8 0 P.O. Box 6WO • HOIU t." MA 01746
• i 0
U. 111 It
E I I DE
A 60% water dispersible granule for use as a pre -emergent weed control in lawns and turf.
ACTIVE INGREDIENTS:
Pendimethalin IN-(1-ethylpropyll-3.
4-dimethyl-2.6-dinitrobenzamine) 60.00
INERT INGREDIENTS:. .... 40.00
-OTAL 10000
(1 pound contains 0.6 hounds of Pend,melnakf
'PRE -FA is a registered trademark of Lesco. Inc
KEEP OUT OF REACH OF CHILDREN
CAUTION
PRECAUTIONARY STATEMENTS
Hazards to Humans
May Cause Eye and Skin Irritation
Avoid contact with eyes. skin and clothing. Wash mo-eughly alter
handling.
FIRST AID: In case of contact. immediately flush eyes or sI, r with plenty
of water.
ENVIRONMENTAL HAZARDS
This product is toxic 10 fish_ DO NOT apply directly to water o eetlands. DO
NOT apply when weather conditions favor unit Isom larger a•ee. DO NOT
contaminate water by cleaning of egmpmenl 0' denosal of vs=_s.
DIRECTIONS FOR USE
it is a violation of Federal law to use this product no a manner-coisistant with Its
labeling.
CHEMIGATION: Do not apply this product through any type of ruination system.
STORAGE AND DISPOSAL
Prohibitions: DO NOT contaminate waterfeed or feed by storage or
disposal. DO NOT store above 120 F.
Pesticide Disposal: Pesticide spray mixlure or rinse wale, r'a: cannot be
used in accordance to label instructions must be disposed of according to
applicable Federal, Stale or local procedures
Container Disposal: Completely empty bag into apphcabo^ equipment.
Dispose of empty bag in a sanitary landlel or by i rcornahon.o, fallowedby
State and local authorities, by burning. If burned. stay our of smoke.
Storage: Store in original containers and keep closed. Store in a cool, dry
place.
MIXING AND APPLICATION INSTRUCTIONS
Add LESCO PRE-M' 60 DG slowly to partially -filled lank V z to'. full) of water wNle
agitating and then fill the remainder of the tank with water. MAINTAIN CONTINUOUS
AGITATION WHILE ADDING LESCO PRE-11,4' 60 DO, If the spray mixture is allowed to
settle for any period of time. thorough agitation is essential to resuspend the mixture
before spraying is resumed. Continue agitation while spraying as needed.
Apply with property calibrated equipment in sufficient water per acre to provide
uniform spray distribution. Low pressure (25-50 psi) sprayers are recommended.
Nozzle screens must be no finer than 50 mesh. Avoid application when winds may
cause drift.
LESCO PRE-M' 60 DG treatments are most effective in controlling weeds when
adequate rainfall or overhead irrigation is received within 7 days after application.
Avoid contact of spray solution with driveways, alone. wood or other porous surfaces.
Rinse immediately to avoid staining.
COMPATABILITY
LESCO PRE -MT 60 DG is compatible with most commonly used herbicides. When
tank mixing be sure to add LESCO PRE-M' 60 DG to the partially filled tank first, mix
thoroughly, and then add combination products to the mixture. DO NOT apply lank
mix combinations unless previous experience indicates the mixture is effective and
will not result in application problems or plant injury. DO NOT attempt to mix LESCO
PRE-M' 60 DG directlywith liquid fertilizer. Premix one parlor LESCO PRE-M" 60 DG
with two parts water and add this diluted mixture slowly into the lank while agitating.
GENERAL INFORMATION
Special Precautions
LESCO PRE I.'
B0 DG Ieatments will not control established weetls. Applications
mos: ^_ =.,
: -, to awmm um, of weeds
TFree aMfca:
o-s pot v ear w may be made. Alloat least 2 months between
c.,....n. c mdioaled under DIRECTIONS FOR USE
i... Doss wah a dense and uniform stand. DO NOT use
0- ^e.. r. >eecee
cr spr,ggeo tufgrass. DO NOT use on wulka-overseed turlgrass.
DC r,_C- .ce `
: amass severely thinned by winter sVess.
LESCOPRE 1:
bit DG provides effective residual weed control f,ch may affect new
1orlg ass Sees
-cl or SM,gs. DO NOT reseed or wmler-overseed lrlgrass within 4
"e,, C.
t, r apulmabon. DO 140T sprig turlgrass within 5 months after
a Pnbca. cn
DO NOT se rcr
cen ut,111 o, dichondra maintained as desirable turf.
NOT FOR USE IN CALIFORNIA
TURF
SPECIES
WEEDS
CONTROLLED
RATES OF
'PRE.M-60 DG
COMMENTS
t•CF.-n E'r r.
__
F`e'z:.a
- .arocrass
Apply in sonic, before
KeCup. Geec'2'i
C"mc'asc
2510331b5.
weetls germinate_
Pe-e^ _ _
r _c.m
Cer Acre
Repeal application If
..a.
r
neceary m 8 weeks or to
ss
Hoc u._..
C 9 to 1 2 oz
51bs per Acre or
_'aye spurge
eq, 1000so .
c 9 oz per 1000 sq it
prow. w,mr,roh
Cuoweea
Gnoseoass
45 m 5.51ps
E,cu, P'rmr Ose
per Acre OR
1 61. 2.0 in
per 1000 On t.
Annual m�egrass 2.5 to 3.31bs
Common cmckweed per Acre OR
furc,cee, chickweed 09 to 1 2 oz
HOInt per 1000 sq.4
I Apply in are summer
' to early fallbefore weeds
1 roommate
SC,_,HEna-
GRASSES
Soma
fiarnvaragras
291.331m,
Apply in spung before
8err.,.,^,acass
Crabmass
per Acre
weeds germinate.
Cel:y'eep=s:
Face pamR:m
or
' Repeal appbcatmn d
St Aucs:= egr.es
Four,
: 0 to 12 oz
necessary., 8 seeks up In
Tau o'ci.e
P,osuele spurge
per 1000 sit h
2.5 fbs. per Acre or
Zo,sam'."
Yellow woodsonel
09 o,, per 1060 sq. I
Cuaweed
Gooself ass
14 5 to 5.5 es
Hop Gower
I per Ape OR
F.renmo Pnm,ose
16 to 2 0 OF
so, 1000 sq. h.
Henbn
25 to 3.316s.
a, -.pry u' G., >r,mer to
Annual blermass
Orr Acre OR
earl, tall lathe weetls
Common cmckeveee
'I J91. 1.2 is,
oermmaN,
Mouseear cNckweed)
per 1000 sit P.
WARRANTY
Lesco warrants that this herbicide conforms to the chemical description on its
label. When used in accordance with label direction under normal conditions.
this herbicide is reasonably fit for its intended purposes. Since timing,
method of application. weather, plant and soilconditions. mixture with other
chemicals. and other factors affecting the use of this product are beyond our
control. no warranty is given concerning the use of this product contrary to
label directions or under conditions which are abnormal or not reasonably
foreseeable. The user assumes all risks of any such use.
E.P.A. Reg. No. 10404-52 Manufactured for:
E.P.A. Est. No. 11773-IA-1 LESCO, INC.
#011 979 —5 x 1011 Case 20005 Lake Road, P.O. Box 16915
#011965 —,D Ib. Bag Rocky River, Ohio 44116
3851201Vr
Rev. 10/87
MATERIAL SAFETY DATA SHEET
tNur•. ,-,-• OH 441
Name and Address: LESCO, Inc., 20005 Lake Road, Rocky River,
Emergency Phone: LESCO: (216) 333.9250 CHEMTREC: (800) 424-9300
LESCO PW-M 60 UH .•.-
Herbicide
ITEM ff:
011965, 011979
IL rhvuu.., ,u".,•• •� - --
Chemical t-amuy
Trade Name
Dinitroanaline herbicide
PRE-M 60 D6 Herbid,lde
Molecular Formula(s)
Common Nam@ & SynOpymS
C13H19N304
I pandimethalin
I11. HAZARDOUS INFORMATION: INGREDIENTS
%(bywt_) CAS9
Chemical Name
60.0 40467-42-1
N_(q:..,thylp+-opyl)-3,4-dimethyl-2,6-dinitrobenzenamine
IV. PHYSICAL AND CHEMICAL CHARACTERISTICS
Specific Gravity (water = 1k NA
Boiling Point: NA
Bulk Density (Ibsdcu. fta: z9-35
Melting Point NA
Evaporation Rate: NA
Vapor Pressure (mmiHg): NA
Percent V018171e: Non-volatile
Vapor Density (air = .1}. NA'
Appearance and Odor. Yellow granules
PP
' .011lit An -Water,: 0lsperses
ubtT.o-1o.0
Nutty odor
pH:
V
Flash Point (Methoq usea): na Upper Explosion Limit: NA
Lower Exploslon'.LhT1W NA PP P
IN Alcohol Foam K7 Dry Chemical
Extinguishing Media: U Foam [) Other ® CO:
® Water Spray _
proved self-contained breathing apparatus and protective
Special Fire -Fighting Procedures: .wear ap
clothing. Highpres'sure;' water spray be
ay may disperse material end spread contamination. Contain runoff
and prevent from entering drains, sewers, ditches, ztreams,or bodies of water. Toxic fumes may
generated under fire conditions.,
Unusual Fire and Explosion Hazards: Not an explosion hazard.
OSHAIPEL or ACGIHITILM Limits: T+7Ncei I ing 5.0 mg/m
Primary Route(s}of'Entry. . skin, eyes, dust inhalation
Signs. & Symptoms, of Exposure
Acute: Moderate eye an :skid irritation. Considered practically non -toxic by single does ingestion.
Chronic: stight'to'moderate eye or skin irritation.
Emergency First -Aid Procedures
If irritation persists, get medical attention.
Eyes: flush vith:waten for 15 minutes.
ve contaminate clothing.
$kill: wash. thoroughly"'wl'th 'soap and water. Remo
Inhalation: p vc td fresh sIr. Call physician or Poison Control.
IngeStl.Of1:,Giwe `M9(assas of milk or water and a saline laxative. Y
1 .'.a.} - o th to an unconscious erson. ARC., rrlCri A1- NO
Il�ve adm, n o potential Carcinoqen (1 0
Oral LDao:'Acute (rat) greater +ban 5,OD0 mg/kg
Medical Conditions Aggravated by Exposure:
lunw.
None known
(ftabbit)
in 2,000 mg/kg
Stability_ (4 Stable ❑ Unstable
Conditions to Avoid:. Do not store above 120oF
Incompatibility:. Avo,l d;,contamf oation with stron oxidizing and reducing agents or strong alkalies
Hazardous Decomposition Products: Possible combustion products include oxides of carbon and nitrogen.
Hazardous Polymerization: %k Will not occur O Will occur
Conditions lo'Avoid: None known
)rSPILL,'LEAK AND DISPOSAL PROCEDURES
If material is spilled: If dry, sweep or shovel into a container for reuse per label instructions or disposal.
If liquid, contain spilt and absorb with inert material and place in a container for disposal. Prevent spill
from entering drains, . sewers; ditches, streams or bodies of water. This product is toxic to fish. Avoid
contact with skin,.eyes, and clothing.
Waste Disposal Method.. Dispose according to federal EPA procedures as outlined in the Resource
Conservation Recovery Act (RCRA) and follow state and focal guidelines.
SPECIAL PROTECTION INFORMATION,
Protective Equipment Suggested for Outdoor Application:
0 Impervious Gloves 0 D,ust Mask O Respirator
® Impervious,.Boots R Clean Clothing RR Eye Goggles/Safety Glasses
Protective Eqf ,prr ent Suggested.for Confined Areas:
f2 Sufficient Ventilation- t7'Respirator 0 Dust Mask fw Splash Goggles
. ® Eyewash Station 53 Emergency Shower D Impervious Apron 0
:1. STORAGE AND HANDLING
Precautions: Store in a cool,, dry place if possible. Separate from other pesticides, fertilizers, seed, feed,
foodstuffs, .drains, sewers and water sources_
Other Precautions: 'Do. not: -store in temperatures above 1200F. Keep out of the reach of children. Do not
store in unmarked containers. wear clean clothing when handling. Keep containers closed when not in use.
Do not breathe or inhalc.dust. To avoid staining, rinse immediately. To reprove surface stains on painted
surfaces, wipe with a cloth soaked in mineral oil. Sunlight will bleach away most outdoor stains within
7-14 days.
(11. MISCELLANEOUS INFORMATION
NA = Not Applicable „ND = Not Determined Date of Issue: 5/15190 Supersedes: it/12/e6
Preparation and distribution of this Material Safety Data sheet
done by LESCO. Inc., 2,OWS. Lake Road, Rocky River, Ohio 44116.
The information contained herein is based on available data However, no warranty is expressed or implied regarding the accuracy of this data
or the results to be obtained from the use, thereof and you should make your own investigation to determine safety for the use you con•
template. LESCO. Inc- makes no'warranty o(.merchantability of fitness for a particular use. nor is there any otherexpress or implied warranty
except as may be specifically provided oth.invise on product
LESCO, Ina assumesno responsibility or liability for any incidental of eonsequantial damages whether related to personal injury *(property - -
damage, to y0114005,.users orthird parties, caused by the material and LESCO, Inc: s responsibility Is limited to replacement of, or repayment
of, the purchase price for the materials) with respect to which any damages are elainl id. All vendfees of usefs assume all risk associated with
the use of the materials). - -
For further information; contact LESCO, Inc- • 20005 Lake Road - Rocky.River, Ohio 44116 or (216) 333.9250.
** TOTAL PRGE.ae3 **
Specimen Label
Dursban Turf
Insecticide
To Be Applied Only by or Under the Direct Supervision of Commercial
Applicators Responsible for Insect Control Programs.
Active Ingredient(s):
Chlorpyrifos [O.O-diethyl 0-(3,5,6-trichloro-2-pyridinyl) phosphorothioate] ............ 44.9%
Inert Ingredients .. ...................... _ ........ _ ...... 55.1 %
Contains 4 pounds of chlorpyrlfos per gallon.
E.P.A. Registration No. 464-524
E.P.A. Est, 464-MI-1
KEEP OUT OF REACH OF CHILDREN
WARNING
AVISO:
PRECAUCION AL USUARIO:
Si usted no lee inglds, no use este producto haste que is
eacuat0 to hays sidd explicada ampliamente.
PRECAUTIONARY STATEMENTS
Hazards to Humans and Domestic Animals
MAY BE FATAL IF SWALLOWED
• ABSORPTION THROUGH SKIN MAY
BE FATAL to CAUSES SUBSTANTIAL
BUTTEMPORARY EYE INJURY
0 CAUSES SKIN IRRITATION
Do Not Get In Eyes, on Skin Or Clothing
a Wear Eye Protection a Avoid Breathing
Vapors And Spray Mist a Handle Concentrate
In A Ventilated Area a When Handling
Concentrate Wear Protective Clothing Such
As Long -Sleeved Shirt, Long -Legged Pants,
Hat, Rubber Gloves And Footwear Resistant
To Aromatic Solvents, i.e. Neoprene Or Nitrile
Butadiene Rubber a Wash Thoroughly With
Soap And Water After Handling And Before
Eating Or Smoking a Remove Contaminated
Clothing And Wash Before Reuse to Keep
Away From Food, Feedstuffs And Water
Supplies
STATEMENT OF PRACTICAL TREATMENT:
If Swallowed: Call a physician or Poison Control Center
immediately. Do not induce vomiting. Contains an aromatic
petroleum solvent. Do not give anything by mouth to an
unconscious person.
It On Skin: Immediately wash with plenty of soap and water.
Get medical attention. It In Eyes: Flush with plenty of water
for 15 minutes. Get medical attention. If Inhaled: Reprove to
fresh air if symptoms of cholinesterase inhibition appear and
get medical anention immediately.
NOTE TO PNYSICIAN: Chlorpyrllos is a cholinesterase
inhibitor. Treat symptomatically. If exposed. plasma and red
blood cell cholinesterase tests may Indicate significance of
exposure (baseline data are useful). Atropine. only by
injection, is the preferable antidote. Oximes, such as
2•PAM/protopam, may be therapeutic if used early: however,
use only in conjunction with atropine. In case of severe acute
poisoning, use antidote immediately after establishing an
open airway and respiration.
Physical or Chemical Hazards
COMBUSTIBLE to Do Not Use or Store Near
Heat or Open Flame. of Do Not Cut or
Weld Container,
Environmental Hazards
This pesticide is toxic to birds and wildlife, and extremely
toxic to fish and aquatic organisms. Do not apply directly to
water. Drift and runoff from treated areas may be hazardous
to equatle organisms in adjacent aquatic sites. Cover or,
incorporate spills. Do not contaminate water by cleaning of
equipment or disposal of waste. This product is highly toxic
to bees exposed to direct treatment or residues on blooming
crops or weeds. Do not apply this product or allow it 10
drift to blooming crops or weeds it bees are visiting the
treatment area.
NOTICE
Read and understand the entire label before using. Use only
according to label directions.
Before buying or using this product, read "WARRANTY
LIMITATIONS AND DISCLAIMER" elsewhere on this label. It
terms are not acceptable, return unopened package at once
to seller for full refund of purchase price paid. Otherwise, use
by the buyer or any other user constitutes acceptance of the
terms under WARRANTY LIMITATIONS AND DISCLAIMER.
Al A FP l_ LS77
Do Not Ship or Store with Food, Feeds,
Drugs, or Clothing
IN CASE OF AN EMERGENCY
endangering life or property Involving this
product, call collect 511•63&4400
DIRECTIONS FOR USE
it is a violation of Federal law w use this product in a manner
inconsistent with its labeling.
Do not formulate this product Into other end -use
products.
GENERAL INFORMATION
Dursban Turf Insecticide is an emulsifiable concentrate
designed for use as a spray to control various pests injurious
to trees, turf and ornamental plants. The pests controlled are
listed in the accompanying tables. Dursban Turf Insecticide
is compatible with insecticides, milicides, and fungicides
commonly recommended except for alkaline materials such
as Bordeaux mixture and lime, A small amount of spray
mixture should be prepared to Mack for compatibility before
a large volume of spray is mixed.
Attention: Do not allow adults, children or pets on treated
areas until spray has dried, Keep out of fishpools and other
bodies of water. Do not treat vegetable gardens. Do not allow
livestock to graze in treated areas. Do not food treated grass
cunings (hay) or seed screenings to livestock nor use hay for
livestock bedding. Do not use in poultry houses.
Turf and Other Outdoor Uses
Use Duroban Turf Insecticide to control the pests listed in the
following table by application at the recommended dosages,
Dilute Dursban Turf Insecticide in water and apply as a
coarse, low-pressure spray using suitable application
equipment. For best results, the lawn should be moist al time
of treatment. Spray when pests first appear; re -treat when
needed. but not more than once every 7 days.
Amount of DTI per
Pestt
Specific Directions
1000 sq. tt,
Acm
Ants (including foraging fire ants)
'V. (I. oz.
i qt.
1. Use Dursban Turf Insecticide for area
Amlyworm (Such as' Beet, Fall,
control of ticks and chiggers infesting
Yettowstdped)
non -cropland areas such as roadsides.
Centipedes
footpaths and trails, ptcnic and camping
Chiggers (1)
sites, parks and other recreational areas
Chinch bugs
where these pasta are present and create a
Crickets
nuisance or a possible public health problem.
Cutworms
Do not allow public use of treated areas
Earwigs
during application or until spray has dried.
Fiery skipper
Apply Dursban Turf Insecticide in water at
1/2
Fire ants (mounds) (2)
the rate of % pint per acre (equivalent to
Fleas
g, oz. per 2,700 sq. %) using a hydraulic
Grasshoppers
sprayer, mist applicator, knapsack sprayer. or
Greenbugs
other suitable hand- or power -operated spray
June beetles
equipment. Treat low underbrush, grassy
Leafhoppers
areas, weeds, and ground surface and
Lucerne moth
debris, using enough spray volume to obtain
Millipedes
thorough coverage. usually 40 to 100 gallons
Miles (Such as, Clover, Bermuda
per acre.
grass stunt, Winter grain)
2. For individual lire ant mounds, apply
Mosquitoes (3)
Dursban Turf Insecticide as a drench.
Pflibugs
diluted at the rate of 1 fl, oz. (30 mq per 4
Sod webworm (4) (lawn moths)
gallons of water.
Sowbugs
Gently sprinkle 1 to 2 gallons of the diluted
Ticks (1)
emulsion over the surface of each mound
using a gentle spray (such as a sprinkler
can). Thoroughly drench mound and
surrounding areas 10 a 2 foot diameter. For
best results. apply in cool weather, 85.80°F,
or in early morning or late evening hours.
Treat new mounds as they appear.
Pressurized sprays may disturb the ants and
cause migration, reducing product
effectiveness.
3. Mosquito" coming to rest on areas treated
for control of turf pests will be killed for
varying periods of time after treatment,
depending on exposure of treated areas to
weathering conditions.
4. For sod weeworms, delay watering or
mowing the peeled area for 12 to 24 hours
after treatment.
European crane fly
1ft. oz,
qt.
Turfgrass weevil (Hypswdesl(t)
11/2 ft. oz.
2 qt,
i. Spray suspected problem areas in mid -April
and again in mid -May. or 89 recommended by
your Leal AgrieufWral E[ten9idn Service
specialist.
Amount of DTI per
posit loop aq. ti. Acre Specific Directions
White grubs (Such as: Black turfgrass
11h to
2 q1.
to 1
1. For white grubs, spray when grubs are
youngsurface,r andactivelynear the
ly
ataenius, European chafer. Southern
3 fl. oz.
gat.
feeing Ise July end August
masked chafer and Japanese
larvae)0)
or as recommended by your local Agricultural
beetle
Extension Service specialist. Immediately
after spraying, Irrlgato the treated $tea
with'/* to 1 Inch of water to wash the
Insecticide Into the underlying Boll.
Bluegrass billbugs(1) i '/• to 1 qt- to I. For bluegrass blllbugs, spray early
311. OZ 1 1 gal. in the season when adults first appear.
Retreat as needed,
tNumbers In parentheses rotor to Specific Directions.
pest Control on Outside Surfaces and
Around Buildings
Apply Dursban Turf IneactlCids by application as a residual
spray to outside surfaces of buildings including porches,
window frames. saves, patios, garages, refuse dumps and
other areas where peals congregate or have been seen,
Repeat treatment as needed to maintain effectiveness, but
not more often then once every 7 days.
-
Amount of DTI
In water to Male:
Peaty
Specific Directions
1
10
so
gallon
gallons I
gallon$
Ants
For Perfineter Treatment (1)
1. To help prevent infestation of buildings, treat a
Bees
band of soil 6 to 10 feet wide around and
Boxelder bugs
'Ax to 'A
Y to 3
4 to 16
adjacent to buildings, also the building
Carpenter ants
fl. oz.
fl. oz.
if. oz.
foundation to a height of 2 to 3 feet, where
Clover mites
pests are active and may find entrance. Use
Cockroaches
4 to 16 fluid ounces of Dursban Turf
Crickets
Insecticide per 50 gallons of water and apply
Earwigs
as a coarse spray at the rate of about 10
Elm leaf beetles (adults)
gallons spray mixture per 1.000 SQ. h. to
Firebrats
thoroughly and uniformly wet the band area.
Fleas
2. For scorpions, remove accumulations of
lumber, firewood, and other materials which
On Outside Sulfates
Flies
Hornets
serve as insect harborage sites. Make a
Millipedes
11/3
131/4
2 qt,
ihoreugh perimeter treatment around the
Mosquitoes
fl. oz.
fl, oz,
structure using directions in (1) above.
Pillbugs
Scorpions (2)
Silverfish
Sowbuge
Spiders
Springtails
Ticks
Wasps
tNumbers in parentheses refer io Specific Directions.
Ornamentals (Outdoor)
Use Dursban Turf Insecticide to treat flowers, shrubs,
evergreens, vines, shade and flowering trees found to be
Infested with peals listed in the following table, Dilute
Dursban Turf Insecticide with water according to directions
given in the table and apply using suitable hand- or Power -
operated spray equipment In a manner to provide complete
and uniform coverage. For best results, apply a coarse spray
to thoroughly wet both upper and lower leaf surfaces and
Infested Ilmb and bunk areas. Attempt to penetrate dense
foliage but avoid overspraying to the point of excessive
runoff. Treat when pests appear and repeat at 7 to 10 day
Intervals, i1 needed. Do not use on fruit and nut treas that will
beer fruit within 1 you of application.
Consult your State Agricultural Experiment Station or
Extension Service specialist for application timing and other
specific use information.
Note: Ornamentals: Dursban Turf Insecticide has been
tested on numerous ornamental plants without causing
serious phytotoxlcity. However, do not use on azaleas,
camellias, poinsettias. rose bushes, or variegated ivy
because of possible injury to these plants.
Paso
Amount of D71
In Water to Make:
Specific Directions
1
gallon
3
gallons
100
gallons
'Al
1A
8
1. For bagworme, treat when insects are in the
Adelgids (Such as: Cooley and
II. oz.
II, oz.
II, oz.
crawler stage.
Eastern spruce galls. Pine bark)
2. For effective Control of leamilers, spray
Ants (Including laagiIV Ilre ante)
should be applied pistons leaves are
Aphids (Such as: Apple,
Chrysanthemum, Cottonwood. Elm
tightly rolled,
last, Peach, Rose, Spires, Woolly)
3. For OWNS COMMI of maple leafcutter on
Armyworms (Such as: Fell,
maple trees, apply spray to larvae as cases
Yellowstripad)
are being formed. Do not treat sugar maple
sagworms(1)
trees, intended for maple syrup production.
Boxelder bugs
4. For effective control of spider mites when
Cankerworms
large numbers of eggs are present, apply a
Carpenter ants(5)
socond spray 3 to S days in the South or 7 to
Catalpa sphinx
10 days in the North after Initial treatment to
Chiggers
control newly-hatChed nymphs.
Citrus mealybugs
5. Locate corpsmen ant nest, if possible, and
Clover mite
drench dtoroughly.
Elm spenwc , ^
e. For control of Fall webwonn, direct spray into
Fall webworrn{6)
web and Immediately adjacent foliage.
Grasshoppers
Green frultworm
Mornworms
Jackpine budworm
Juniper webworrn
Katydids
Lace bugs
Leaftloppers
Leafmilem(2)
Maple IeatMter(3)
Mites (such as: Red spider.
Southern red)(4)
Oleander caterpillar
Orange tortrix
Periodical cicada
Plant bugs
Poplar tentmaker
Psyllids
Puss Caterpillar
Rose chafer
Sawflies exposed (Such act:
Pine, Pin Oak Redheaded)
Sowbugs
Spittlebuge
Spring elm Caterpillar
Spruce budxronn
TSnt caterpillars (Surly as:
Eastern, Forest.' Western)
Thornbug
Walnut caterpillar
Western spruce budeorm
Whiteffiee
Yellownecited caterpillar
?Numbers in parentheses refer to Specific Directions
PIP FP LRFELS US so
Amount of DT1
In Water to Make:
Peatt
Speciho Directions
1
3
100
gallon
gallon$
gallons
Armyworms (Beet)
1/t
'A
u, oz-
1 pt.
1. To reduce twig and branch feeding by bark
beetles, applications should be made in the
Beetles (Native elm bark)(1)
ft. oz.
spring or early summer.
Cutworms
Leafhoppers
2. To kill migrating and invading gypsy moth
Mahogany wobwonn
larvae, creel trunks and foliage.
Mealybugs
3. Bleckvine wasvils are night feeders, Late
Mimosawebwonn
afternoon spraying will give control in some
Moths (Such as: Browntaii. Cypress
areas.
lip, Douglas fir tussock, European
pine shoot. Gypsy(2). Holly bud,
Nantucket pine tip, Pandora. Pitch
pine tip. Subtropical pine tip,
'tussock)
oakwonns (Such as: California,
Orangestriped, Redhumped)
Redhumped caterpillar
Thripe(exposed)
weevils (Such as: Slackvine(3),
Yellow Poplar, Pine reproduction)
Foliar feeding beetles (Such as: Water
'A to
1f4 fl,
'A to
1 ft. oz,
1 pt. to
1 qt.
1. For cottonwood leaf beetles, use
Dursban Turf Insactickia In water to
1e8t(1), Elm leaf. Flea, Fuller rose.
Japanese. June, Wulow leaf)
oz.
control larvae and adults infesting
cottonwoods. Make the treatment when field
counts indicate damaging beetle populations
-
are developing or present.
Borers(ly Clestwing moths (Such as:
ya fl, oz.
1 0. oz,
1 ql.
1. For Doren, apply Oursban Turf Insecticide
to the trunks and lower limbs of trees and
Ash, Dogwood, Lesser peachhee,
Lilac, Oak, Rhododendront•
shrubs when the adults begin to emerge.
Metallic wood (Such as: Bronze
Consult your State Agricultural Expartmem
Station or Extension Service specialist for
birch, Flatheaded epptetree,
Twolinad chestnut), LOnghornsd
proper time to treat. Apply uniformly as a
beetles (Such as: Locust, Red oak)
coarse, low-pressure spray.
Cranberry girdler lame(2)
2. For cranberry glydlw larvae, apply
L.eahntners
1 quan of Dursban Turf Insecticide per
Needleminers (Such so: Jeffrey pine.
acre. Direct spray at the base of tree using
Lodgepole pine, Spruce)
5o galkxe of water per we. Irrigate
Scale crawlers (Such all;
immediately after application for sou
CoWnyatshion, Coaonyntaple,
penetration of 1.2 Inches. Treat alter egg
Euonymus, Fletcher, Florida wax,
laying during the summer.
Golden oak, Hemispherical.
Lecanium, Magnolia, Oak kermes,
Oystershell. Pine needle, San Jose,
Tea, White birch)
Borers (Such as: Cottonwood,
1 fl. 02.
3 e, oz,
3 qL
1- For Peachtree bdtera, apply Dursban
Turf Insecticide In water to flowering trees and
Peachtree) (1)
shmbe of the genus Pruran as a trunk spray
before newly -hatched larvae enter the frees.
Apply as a chars$. low-pressure spray.
Thoroughly wet all bark areas from ground
level to sca0old limbs.
8ee0e3(1) (Such as: Cottonwood teal,
1%
4 0. oz.
1 gal.
1. For preventive 119811TWI, apply the spray to
the main trunk of trees in the early spring or
Elm leaf, Flea. Fuller rose, Native
elm hark(2). Willow leaf)
0, oz
when threat of anack exists from nearby
Infested trees. For 1e11ad101 treabnerd,
apply the spray to the main trunk of infested
bees or logs when damage occurs but before
adult boo" begin to emerge.
2. To prevent native elm bark beetles
from overwimeri g to uninfected bees, apply
Dunbar TbA Insecticide In *star to ttre
bottom 9 feel of the trunk, Wet the trunk
thoroughly but do not spray to runoff. Can
should be taken to apply the spray right to the
base of the root flare. Application can be
made with either a backpack mlstblower or a
hydraulic pressure sprayer from spring
through to early fail.
Amount of OTI
In Water to Make:
ik' iil
Wood infesting beetles (Such as: 2'h 811. oz.
Ambrosia. Anoblidae, Black fl. oz.
turpentine, European elm bark.
Japanese, June, Southern pine,
Spruce)(1)
tNumbers in parentheses refer to Specific Directions
Dormant Spray (Tree Pests)
Use Dursban Turf Insecticide as a dormant or delayed
dormant spray at the rates indicated to control the listed
insects. Spray the entire tree to dampen using suitable
ground spray equipment. Use the higher dosage of Dursban
Turf Insecticide for severe infestations. Use oil as
recommended by your State Agricultural Experiment Station
or Extension Service specialist.
Restrictions: Make only one application during the dormant
season. Oo not allow meat or dairy animals to graze In
treated areas.
Specific Directions
gallons
2 gal, 1. For preventive treatment, apply the spray
to the main trunk of trees in the early spring
or when threat of snack exists from nearby
infested trees.
For remedial treatment, apply the
spray to the main trunk of infested trees
when damage occurs but before adult beetles
begin to emerge,
Amount of DTI
In water to Make:
Pestt 1 3 100 Specific Directions
gallon gallons I gallons
Aphids (Such as: Meaty plum, ROSY 1Ax to 1/1 to 1h to Tank mix with 1 to 2 gallons of petroleum spray
apple, wooly apple) fh 11. oz. 1h It. oz. 1 pt. oil recommended for dormant use in 100 gallons
Borer (Such as' Peach twig) of water.
Cutworms (Such as: Climbing)
Leafrollers (Such as: Pandemis)
Poor psylla adults
Plant bugs
Scale (Such as: San Jose) _......
STORAGE AND DISPOSAL
Do not comaminate water. food or feed by storage Of
disposal.
Stoops: Store in original container in seared dry storage
area. Prevent cm5s•conmmination with other pesticides and
fertilizers. Do not Store above 1WF la extended periods Of
time. Storage below 20°F may result in formation of crystals.
If product crystallizes, Store at So to 701F and agitate to
redissolve crystals. if container is damaged of Spill occurs,
use product immediately or dispose of product and damaged
container as indicated below.
pesticide DUposal: Pesticide wastes are toxic, improper
disposal of excess pesticide, spray mixture, or tinsate is a
violation of Federal Lew. It these wastes cannot be disposed
of by use according to label instructions, contact your State
Pesticide or Environmental Control Agency. or the Hazardous
Waste representative at the nearest EPA Regional Office for
guidance.
Container Disposal: Mote rinse (or equivalent). Then offer
aasa�ry landfill, or Cy ahaPorowdupuncture
reappppdispose by State
te
and local authorities -
WARRANTY LIMITATIONS AND
DISCLAIMER
The Dow chemical Company warrants that this product
conforms to the chemical description on the label and is
reasonably fit for the purposes slated on the label when used
In strict accordance with the directions therein under normal
conditions of uss, IS THE ONLYWARRANTY
ON THIS RT.ODUCINO OTHER EXPRESS AND NODE
IMPLIED WARRANT! OF MERCHANTABILITY OR
FITNESS FOR A PAR11CULAR PURPOSE IS MADE
OUTSIDE OFTHIS LABEL Therefore, neither this warranty
nor any other warranty of merchantability or fitness for a
particular purpose, express or implied. calends to the use or
this product contrary to label instructions (including
conditions noted on the'"- such as unfavorable
temperatures, soil OOndri 011C atc-), under abnormal
conditions (such as excessive rainfall, drought, tornadoes,
hurricanes, etc.) or under conditions not reasonably
foreseeable to or beyond the control of seller.
C, J
Gl
PIP FP LABELS US $
When buyer or user suffers losses or damages resulting from
the use or handling of this product (including claims based
on contract, negligence, strict liability, or other legal theories),
buyer or user must promptly nobly in writing The Dow
Chemical Company of any claims to be eligible to receive
either remedy given below. The EXCLUSIVE REMEDY OF
THE BUYER OR USER and the LIMIT OF LIABILITY of The
Dow Chemical Company or any other seller will be one of the
following. at the election of The Dow Chemical Company!
(1) Refund of purchase price paid by buyer or user for
product bought. or
(2) Replacement of amount of product used.
The seller will not be liable for consequential or
incidental damages or losses.
The terms of this Warranty Limitations And Disclaimer cannot
be varied by any written or verbal statements or agreements.
Any employee or sales agent of the seller is not authorized
to vary or exceed the terms of this Warranty Limitations And
Disclaimer in any manner.
03377-1.12 0989
RO/INSECTICIDE LIQUID N.O.S.
(Chlorpyrifos)
NA1993
. a
THE DOW CHEMICAL COMPANY
Midland, Michigan 48674 U.S.A.
-Trademark of THE DOW CHEMICAL COMPANY
1A FP ABELS US
REVISIONS INCLUDE:
1) REVERTING BACK TO PRIOR
REGISTRATION NUMBER 464-524.
SPECIMEN LABEL 86-1894 DATE CODE C989 REMOVING ALTERNATE BRANDNAME
REPLACES 86-1894 DATE CODE B1288 DURSBAN TURF UNDER E.P.A. REG.
DISCARD PREVIOUS SPECIMEN LABELS NO.464-360.
AIA FP LABELS US 841
r e T E R I A L S A F E T Y C A T A S H E E T
- - - - - - - - - - - - - - - - - - - - - - - - - - -- - -- ------------------
CL- CHEMICAL J.S.A.* MICLANC9 ML 48674 EMERGENCY PFCNE: 511-636-4400
oRCCUCT CCCE: C3377
FRCCLCT P1nMc: CUR5301 (RI TURF INSECTICICc
PAGE: 1
;FFECTIVE CATE: ^6/1Z/9C DATE PRINTED: 11/15/90 MSO: C00974
1. INGRECIENTS: (Y W/W9 UNLESS CTHERwIS� NCTECI
G,Q-CIETHYL C-439596-
TRICHLORC-2-PYRICNYLI PHCSPHCRCTHICATE,
(CHLORPYRIFOSI CASH CO2921-98-2 44.91
INERT INGRECIENTSITCTALI9 INCLUCING: 55.1i
XYLENE-RANGE AROMATIC SOLVENT CAS0064742-95-6
XYLENE(11 CAS"OC133C-2C-7
LvZv4-TRI4ETHYL8ENZENE(11 CASO00009S-63-6
CUMENE(ll CASCOGO098-62-9
PROPRIETARY EMULSIFIERS
(LICCMPONEENT OF XYLENE-RANGE AROMATIC SOLVENT
THIS OCCUMENT IS PREPARED PURSUANT TO THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 191091200)9 IN AOOITICNq CTHER
SUBSTANCES NOT 'HAZAROCUS' PER THIS CSHA STANCARD MAY 9E LISTED.
WHERE PROPRIETARY IAGREDIENT SHCWS9 THE ICENTITY MAY BE MADE
AVAILABLE AS PROVICEC IN THIS STANDARD.
2. PHYSICAL DATA:
BOILING POINT: 2909 143C
YAP PRESS: <10 MMHG 4 25C
VAP DENSITY: NOT OETERMINEO
SOL. IN WATER: EMULSIFIABLE
SP9 GRAVITY: 19079
APPEARANCES YELLOW LIQUID
ODOR: SCLVENT-TYPE OOCR
i. FIRE AND EXPLOSION HAZARD DATA:
FLASH POINT: 106F9 41C
METHOD USED: TCC
FLAMMABLE LIMITS
LFL: LS
UFL: 6% (XYLENE RANGE AROMATIC SOLVENT)
EXTINGUISHING MEDIA: FOA109 CC29 DRY CHEMICAL
FIRE 6 EEXPLOSION HAZARDS: FOAM FIRE EXTINGUISHING SYSTEM IS
PREFERRED BECAUSE UNCCNTRCLLEC WATER CAN SPREAD PCSSIBLE
lLw,.TINUEO ON PAGE 21
(R) INCICATES A TRADEMARK OF THE DCW CHEMICAL CCMPANY
o AN OPERATING UNIT OF THE OCW CHEMICAL COMPANY
AIA EC 44 HSDS AM 44
A " E R I A L S A F E T Y C A T A S H E E T
------------------------------------------------------------------------
=CW CHEMICAL U.S.A.a MICLANC. MI 48674 EMERGENCY P14CNE: 517-636-44CC
c RCCUCT CCCE: C3377 PAGE: 2
v RCCUCT NAM--: CURS3AN (R) TURF INSECTICICE
EF-ECTIVE OAT_: C6/12/9C :.ATE PRINTEC: 11/15/SC MSD: CC--974
FIRE ANO --XPLCSICN HAZARC DATA: (CCNTINUE01
CONTAMINATION. TCXIC IRRITATING GASES MAY BE FCRMEC UNCER
FIRE CCNOCTIGNS. RAPIC CECCMPOSITICN AaCVE 320-392F 116C-
200C) CAN OCCUR. VICLENT RUPTURE DUE TO CVERPRESSURIZATICN
MAY OCCUR AT TEMPERATURES GENERATED DURING A FIRE.
FIRE -FIGHTING EQUIPMENT:
BREATHING APPARATUS.
4. REACTIVITY DATA:
USE PCSITIVE-PRESSURE SELF-CCNTANUED
STABILITY= (CONOITIONS TO AVOID) AVC10 HEATING AaCVE SOC (122F).
CHLORPYRIFOS UNDERGOES EXCTH£RMIC CECOMPOSITICN AT APPRCXIMATELY
130C (266F) WHICH CAN LEAD TO HIGHER TEMPERATURES AND VIOLENT
DECOMPOSITION IF GENERATEC HEAT IS NCT REMOVE[. CONTAINS
PETRCLEUM DERIVATIVE SOLVENT - WILL BURN.
INCOMPATIBILITY: (SPECIFIC MATERIALS TC AVCIC) NONE KNOWN.
HAZARDOUS DECOMPOSITION PRCDUCTS: UNDER FIRE CONDITIONS. HYDROGEN
CHLCRIOE. ETHYL SULFIDE• CIETHYL SULFIDE AND NITRCGEN CXICES CAN
BE FCRMED.
HAZARDOUS POLYMERIZATICN: 4ILL NOT CCCUR.
ENVIRONMENTAL AND DISPOSAL INFCRMATION:
ACTICN TO TAKE FOR SPILLS/LEAKS: ABSORB SPILLS WITH AN AESCRBENT
MATERIAL SUCH AS HAZORB• ZCRBALL. CR DIRT. THOROUGHLY WASH
BODY AREAS WHICH COME INTC CONTACT WITH THIS PRODUCT. CCNTAIN
SPILL TO KEEP OUT OF SEWERS. FOR LARGE SPILLS• CCNSULT
MANUFACTURER.
DISPOSAL METHOD: DO NOT CONTAMINATE FOOD, FEED. OR WATER BY
STORAGE OR DISPOSAL. PESTICIDE WASTES ARE TOXIC. IMPRCPER
DISPOSAL OF EXCESS PESTICIDE• SPRAY MIXTURE, CR RINSATE IS A
VIOLATION OF FEDERAL LAW. IF THESE WASTES CANNOT BE CISPCSED
CF BY USE ACCORDING TO LABEL INSTRUCTICNS, CONTACT YOUR STATE
PESTICIDE OR ENVIRCNMENTAL CONTROL AGENCY, CR THE HAZARDOUS
WASTE REPRESENTATIVE AT THE NEAREST EPA REGIONAL CFFICE FCR
GUIDANCE.
(CONTINUED ON PAGE 3)
(R) INCICATES A TRADEMARK OF THE DOW CHEMICAL CCMPAKY
AN OPERATING UNIT CF THE OCW CHEMICAL COMPANY
PIP EG 44 MSDS RM 45
"in EC 44 MSDS RM 46,
RIA EC 44 MSDS Rh/ 471
-1. , 1' .1.1Y VMII WV I1C V1 W L'C� Ll.l IUrV ANT
PIP EC 44 MSDS RM 49
A T E R I A L S A F E T Y C A T A S H E E T
-------------------------------------------------------------------
-Cm CHEMICAL U.S.A.* MICLANGv MI 49674 EMERGENCY PHONE: 517-636-44CO
:RCCCCT COCE: C3377
;:RCCUCT NAME: CURSBAN (R) TURF INSECTICIDE
PAGE: 7
SFFcCTIVE DATE: C6/12/9G )ATE PRINTEC: 11/15/90 MSO: CCO974
:EGLLATGRY LNFORMATICN: (NOT MEANT TO 2E ALL-INCLUSIVE-- SELECTEC
7EGLLATICNS REPRESENTE0.1
�.CTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH ANC
'SLIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABCVE.
-0NEVER9 NO.WARRANTY9 EXPRESS CR IMPLIED• IS GIVEN, REGULATCRY
2ECUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE
LOCATICN TO ANOTHER; IT IS THE BUYER4S RESPONSIBILITY TO ENSURE
THAT ITS ACTIVITIES COMPLY WITH FEDERAL• STATE OR PROVINCIAL•
AND LOCAL LAWS. THE FOLLOWING SPECIFIC INFORMATICN-IS MADE FOR
THE PLRPOSE OF COMPLYING 'WITH NUMEROUS FEDERAL* STATE OR PRGVINCIAL9
AND LOCAL LAWS AND REGULATIONS. SEE "SO SHEET FOR HEALTH AND
SAFETY INFORMATION.
L.S. REGULATIONS
SARA 313 INFORMATION: THIS PROOLCT CONTAINS THE FOLLOWING SUBSTANCES
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 CF TITLE III OF
THE SUPERFUNO AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR
PART 372:
:HEMICAL NAME CAS NUMBER CONCENTRATION
_----------------.--------------------_---_------------------------------
1#294-TRIMETHYLBENZENE 000095-63-6 5 - 15 %
CUMENE 000098-82-8 1 - 5 2
xYLENE (MIXED ISOMEY I- 001330-20-7 1 - 5 2
SARA HAZARD CATEG01R ;MIS $*OOUCT HAS BEEN REVIEWED ACCORDING TC THE
EPA "HAZARD CATEGORIESO PROMULGATED UNDER SECTICNS 311 AND 312 OF THE
SUPERFUNO AMENOMENT AND REAUTHORIZATION ACT OF 1986 (SARA TITLE III; ANC
IS CONSIOEREDv UNDER APPLICABLE CEFINITICNS9 TO MEET THE FOLLOWING
CATEGORIES:
AN IMMEDIATE HEALTH HAZARD
(CL...INUEO ON PAGE 91
(R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
a AN OPERATING UNIT OF THE DOW CHEMICAL COMPANY
A1R EC 44 MSDS RH 59
A T=? I A L S A F E T Y C A T A S H E E T
------------------------------------------------------------------------
DC4 CncMICAL U.S.A.= MICLANO, MI 43674 EMERGENCY PhCNE: 517-636-44CO
=ZcOLGT CCr;E: C3377
FRGCUCT NANa_: C'J°S34N lRl TURF INSECT IC ICE
PAGz-: e
:PF-CTIVE ;AT_: C6/12/90 DATE PRINTEC: 11/15/9C MSC: CCC974
�E,LLATCRY INFCRMATICN:(CCNTINUEC)
a CELAYEO HEALTH HAZARD
a FIRE HAZARD
(R) INDICATES A TRADEMARK OF THE DOW CHEMICAL CGMPANY
THE INFORMATION HEREIN IS GIVEN IN GOCD FAITH♦ BUT AC WARRANTY9
EXPRESS CA IMPLIED• IS MACE, CONSULT THE COW CHEMICAL COMPANY
FCR FURTHER INFORMATION.
a AN CPERATING UNIT OF THE DCW CHEMICAL COMPANY
RIP EC 44 MSDS AM 51
• 32-5=7 Fertilizer
with Dursban*
For the control of soil insects such as ants, armywofms, cut worn,, sod wetlworms, chillchhuys, earlsigat,
sowtiugs and crickets.
CONTAINS NEW LOW ODOR DURSBAN'
ACTIVE WGRSOIENT:
Chlcrpyrilos (O. OdieNyl-O-(3,S.rtricMorw2- -
pydayllphospnorothioate 1...................... ........ ................ ,................. �07a%
INERT INGREOIENTS: _...... ............................... _..._.........._..... 98.2ri%
......_....70TAL................................................. t00.00% i
DURSBAN'.- Registered Trademark of Dow Chemical Company
U.S. Patent No. 3,244,586
:J1 GUARANTEED ANALYSIS
TOTAL NITROGEN (N)' ...,... ...............32.
......................
1.06%Ammbniacal Nitrogen
18.94%Ursa Nitrogen
12.00%Coated Slow Release Urea Nitrogen , ,6.00%
AVAILABLE PHOSPHORIC ACID (P20$) .. . .... . ..................... . , , . , 100%
SOLUBLE POTASH (K20) ...... . ............................. . ............fi.40%
SULFUR (S) (Free). . ........ ................ ....
INGREDIENTS: Sulfur Coated Urea, Urea, Ammonium Phosphate, Muriel$ of Potash.
,50% of the Nitrogen is derived from Lesco Sulfur Coated Urea.
'KEEP OUT OF REACH OF CHILDREN
CAUTION
Read All Directions Before Using
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
CAUTION: May be harmful it swallowed. Avoid eye ContacL Wash
thoroughly after handling. wash contaminated clothing
before rausa. Flush contaminated eyes with plenty of.
watOr.and got medical attention if irritation persists.
Keep away from food, foodstuffs and domestic water
supplies. Keep children and pets off of treated area until
Watered Into soil and Boll is dry.
STATEMENT OF PRACTICAL TREATMENT
If awallofaed: Orink i or 2 glasses of water and induce vomiting by
toucri ng back of throat with linger. Call a physician.
It on skin: Wash thoroughly with Soap and w414f.
N In wywe: Flush syea with plenty of water. 0 irritation PersistS, call
a physician.
NOTE TO PHYSICIAN:ACtive ingredient is a cholinesterase Inhibitor.
Treat symptomatically. Atropine only by Injection is an antidote.
ENVIRONMENTALNAZAROS
This product is toxic to fish, birds and other wildlife. DO not apply
directly to water. Fish and crustaceans may to killao it their waleM
we contaminated with this product, DO A01 contaminate water by
cleaning of e0uipment or disposal Of wastes.
DIRECTIONS FOR USE
It is a vlolation of Federal law to use this product in a manner inconsis-
tent with Its labeling.
CHEMIOATIQNC Oo not apply this product through any type of
irrfgation system.
STORAGE AND DISPOSAL
rwetickle storage
Keep out of reach of children and animals. Sulfa In oriGIAM comalnats
only. Store in a cool dry pace W avoid excess heat, C4rehl0y open car
talrora. In rase of spill. Avoid dCntact, twists at" and keep out aMmeN
and uAprotacted parsons. COnllne spills.
psatickso DlepesN
00 nut comaminstewater, food "too by stofage or dMpoaal. Peadotda
waste erewxl0. Improperdisposal of excess Pen16166-l* aym1xWre,"
,,A"le isavlafallon of Federal law, II tnesewastuw,not bedlapo"d W
by use according to tabor Instruction, "Ofdct your State P44WAde or
Environmenud Control Agency. or the Haxerdau Wute rpreeensm" e
at the nearest EPA Regional ORtoe for guldano,
ConWtr Disposal
CompMtNYemply bag into application equipment. Thondia{geadGrii
bag in aunitarylandfill of by incinefallon,ggl/allowed bystate and local
aumotdlee, by burning. It burn60 stay out of alpoke.
NOW TO use
To control rAlpen bugs, Bed wabwonrS, anti, Winyworms, crickets, tut wormsi
urwlge, and wwli uniformly 1pptY3./ pounds of thla product (Dower 1.000
squarateMolroftuvop fur/greuuu.Tnalrhenineectalkaleppaarratreataa
neadad, TO help abtainuneorrn distribution. apply onsJW(ths ra0ulf ad amount
of pi oductlnons die t,0110 i then apply balance At a right shills. Immsdknay anH
application, thoroughly "ter the treated NOW waan1helnaa01101d4 lmo"'Vone
of insect Infestation- '
APPROXIMATE LESCO ROTARY SPREADER SETTINGS
l� too so. a SAUA
3A 1.0
*40 van ANT: a.wto e W caliwee„ ly WD, radde, Axe sae ma0"60Mip,weaa tMuuse
.the vwietl0,e Bit aura,o ealibrew pw W !sear with eem ep01kaaon
WARRANTY
lEafA wRrrW wn lM,naedda wdmnt N tie dee<Y aXMO. of b IWIL law, wad h
,Yrgdenw,M lied rearms sneer nwm,110141 L tNii.waieak fealwaby a W ai,lr�
ae plomm 3iro taws. •,fed d rdDkaan..wPw. *K will wr mn•tow, rNnW will
saw ditalipw.eMaW hdanaa<una" sit dtheD,m [webinofO"Conti. m sera"
a yaw, mwnketo via d des pawn ranker to kbN d'vaaae w~ Una"
abwea a nd,aemav W,4"*. Pa ww swans al rda d"wa, W
Rau. Wit 3190
Maas in U.s&
Manufactured BY Net WgL 50 Lbs.
E.P.A. Reg. No. 10404-29 (22.7 Kg.)
ERA. Eat. No, 10404-OH-02 LESCO, INC.
#016424 20o0S Lakin Road, P.O. Box 16915
Rocky River, Ohl* 44114
• PRODUCT NAME:
LESCO Fertilizer with Dursbano
MATERIAL SAFETY DATA SHEET ITEM #:
Many
I. MANUFACTURER:
Name and Address: LESCO, Inc., 20005 Lake Road, Rocky River, OH 44116
Emergency phone: LESCO: (216) 333-9250 CHEMTREC: (800) 424-9300
11. PRODUCT IDENTIFICATION
Trade Name: Chemical Family:
LESCO Fertilizer with Dursban® Organophosphorus Insecticide
Common Name & Synonyms Molecular Formula(s)
Chlorpyrtfos plus fertilizer CBH,,O,PSNCL. , fertilizer
Ill. Hazardous Information: Ingredients:
Chemical Name % (by weight) CAS #
0,0-diethyl-O-(3;5,6,4richloro-2-pydctyl)phosphorothloate 0.42-0.97 2921-813-2
Inert Ingredients ,(fertilizer)
Urea and/or 99 57-13-6
Monoammonium.phosphate 7784-30-7
Munate of Potash 7447-40-7
Calcium Carbonate 1317-65-3
Potassium sulfate. 7732-18-5
IV. PHYSICAL AND CHEMICAL CHARACTERISTICS
Bolling Point: Decomposes (urea) Specific Gravity (water=1). NA
Melting Point: 1339 C (urea) Bulk Density (Ibs./cu. ft.):45.60
Vapor Pressure (MM, Hg): NA Evaporation Rate: NA
Vapor Density. (air = 1): NA Percent Volatile: Minimal
Solubility In Watrur:Part,IW Appearance and Odor:Mufticolored granules
pH: ND Mercaptan-type odor
V. FIRE AND EXPLOSION: HAZARD. DATA
Flash Point (method, Used):NA (non-flammable) Auto Ignition Temperature: NA
Lower Explosion Limits: NA Upper Explosion Limits: NA
Extinguishing Media:. [XI Foam [X] Alcohol Foam [ ) Dry Chemical
Vq] Water Spray [ ] Other (X] CO,
Special Fme-FigMing:Procedures: Use NIOSH/MESA approved self contained breathing aparatus and protective
clothing. Foom;systent is preferred because uncontrolled water can spread possible contamination. Elevated
temperatures may decompose fertilizer to cyanunc acid, ammonia or hydrogen cyanide. Guard against falls -
sllppery when. waL Prevent runoff or material from entering drains, sewers, ditches, streams or bodies of water.
Unusual Fire and Explosion Hazards: Wet urea can hydrolyze to corrosive ammonia carbonate. Not an explosion
hazard unless mixed with strong acids or high nitrate fertilizers. Toxic and Irritating gases may be formed above
160 - C (320 - F)
VI. HEALTH HAZARDS
OSHA / PEL.or ACGIH / TLV Limits: Chlorpyrifos: ACGIH TLV and OSHA PEL are 0.2 mg/m9, skin.
Primary Route(s) of Entry: Skin, eyes, inhalation of dust, Ingestion.
Signs & Symptoms of Exposu re
Acute: Moderate skin and eye Irritant. Cholinesterase Inhibition - Incoordination, tremors, abdominal cramps.
Chronic:Cholinergerlc effects-dlzzlness, nausea, headache, muscle spasms, diarrhea, salivation, pinpoint pupils.
Emergency Fhst-M.Prooedures
Eyes: Flush with water for 15 minutes. Get medical attention If Irritation persists.
Skin: Remove contaminated clothing. Flush with plenty of soap and water for 15 minutes.
Inhalation: Remove from dust to fresh air.
Ingestion: Administer water, Induce vomiting and call a physician or Poison Control Center. A Cholinesterase
Inhibitor. Atropine by intravenous administration Is antidote of choice. Check serum and/or RBC cholinesterase
levels.
Positive Animal Carcinogen (NTP): No Potential Carcinogen (IARC or OSHA): No
V11. TOXICITY INFORMATION
Oral LD,,:Acute (rat) over 2000 mg/kg Dermal LD,:(rabbit) greater than 2000 mg/kg
Acute Oral LC„ (rats) Is. over 1.6 mg/Ilter for 4 hours.
Medical Conditions Aggravated by Exposure: Low blood cholinesterase levels.
SARA Title III Sec. 311 and 312. This product Is considered, under applicable deflnitions, to meet the following
r.Manrl— An irMrntiltnew "-4N i.....-" --A ..
Vlll. REACTIVITY
Stability: [XI Stable [ ] unstable
Conditions to Avoid: Storage near open flame or wet storage areas.
Incompatibility: Strong acids or caustic compounds.
Hazardous Decomposition Products: Ammonia, HCN, NO„ CO,, cyanuric acid, ethyl sulfide, dlethyl sulfides.
Hazardous Polymerization: [X] WIII not occur [] Will occur
Conditions to Avoid: None known
Chlorpydfos,undergoes exothermic decomposition at approximately 13o' C (266' F).
IX SPILL, LEAK, AND DISPOSAL PROCEDURES
If material Is spilled: Containspill, sweep or vacuum and place in a container for reuse per label instructions or
disposal. Do not allow to enter sewers, drains, ditches, streams or bodies of water. Wear adequate clothing and
do not breathe. dust Sweep area well before reuse. Remove contaminated clothing and wash thoroughly.
waste Disposal Method: Dispose according to Federal EPA procedures as outlined in the Resource Conservation
Recovery act .(RCRA), and follow state and local guidelines.
X. SPECIAL PROTECTION INFORMATION
Protective Equipment Suggested for Outdoor Application:
[X] Impervious Gloves [ ] ,Dust Mask [ ] Respirator
[X] Impervious Boots [X] Clean Clothing [X] Eye Goggles / Safety Glasses
Protective Equipment Suggested for Confined Areas:
[X] Sufficient Ventilation [ IRespirator ]X] Dust Mask [X] Splash Goggles
[X] Eyewash Station [X] Emergency Shower [ ] Impervious Apron []
XI. STORAGE AND HANDLING
Precautions: Store Ina cool, dry. place If possible. Separate from other pesticides, fertilizers, seed, feed, foodstuffs,
drains, sewers, and water sources.
Other Precautions: This product Is toxic to fish, birds and other wildlife. Do not contaminate water or apply where
runoff Is likely Ao :occur. Keep out of the reach of children. Wear dean clothing when handling. Keep container
closed when not In use. Do not store in unmarked containers. Keep area as dust free as possible. Store in
temperature: below.160 *,F (38 ° Q.
)(II. MISCELLANEOUS INFORMATION
NA =.Not Applicable NU = Not Determined Data of Issue. 5/1/92 Supersedes: 11/1/85
Preparation.and.disMbution of this Material Safety
Data Sheet done by. LESCO. Inc., 20005 Lake Road,
Rocky River,. Ohio 4411S.
The Information contained trereln Is based on available data. However, no warranty is expressed or implied regarding
the accuracy of this data or the results to be obtained from the use thereof; and you should make your Investigation
to determine safety for the use you contemplate. LESCO, Inc. makes no warranty of merchantability of fitness for
a particular use, nor is there, any other express or implied warranty except as may be specifically provided otherwise
on product
LESCO, Inc. assumes no:responsibilfty or liability for any incidental or consequential damages whether related to
personal Injury or property damage, to vendees, users or third parties, caused by the material; and LESCO, Inc.'s
responsibility is limited to replacement of, or repayment of, the purchase price for the material(s) with respect to
which any damages are claimed. All vendees or users assume all risk associated with the use of the mateftl(s).
For further information, contact: LESCO, Inc., • 20005 Lake Road r Rocky River, Ohio 44116 or (216) 333-92M
** TOTRL PRGF.BO,q **